Upper Levels: EC1.-.-.- Oxidoreductases. : EC1.1.-.- Acting on the CH-OH group of donors. : EC1.1.1.- With NAD(+) or NADP(+) as acceptor.
D-gluconate:NAD(P)+ 5-oxidoreductase
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Systematic Name
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D-gluconate:NAD(P)+ 5-oxidoreductase
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Common Name
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- gluconate 5-dehydrogenase
- 5-keto-D-gluconate 5-reductase
- 5-ketogluconate 5-reductase
- 5-ketogluconate reductase
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NAD+ + D-Gluconic acid = NADH + 5-Dehydro-D-gluconic acid
(links: NAD+ + (2R,3S,4R,5R) -2,3,4,5,6-pentahydroxyhexanoic acid = NADH + (2R,3S,4S) -2,3,4,6-Tetrahydroxy-5-oxohexanoic acid)
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NAD+
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<Mapping> AtomMap:BMCCPUAPt031$BMCCPUAPt032$0
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NADH
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1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 6 ↔ 6 7 ↔ 7 8 ↔ 8 9 ↔ 9 10 ↔ 10 11 ↔ 11 12 ↔ 12 13 ↔ 13 14 ↔ 14 15 ↔ 15 19 ↔ 19 20 ↔ 20 21 ↔ 21 22 ↔ 22 23 ↔ 23 24 ↔ 24 25 ↔ 25 26 ↔ 26 28 ↔ 28 29 ↔ 29 30 ↔ 30 31 ↔ 31 32 ↔ 32
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(2R,3S,4R,5R) -2,3,4,5,6-pentahydroxyhexanoic acid
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<Mapping> AtomMap:BMSUM6U0--07$BMSUM6Up--08$0
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(2R,3S,4S) -2,3,4,6-Tetrahydroxy-5-oxohexanoic acid
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1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 6 ↔ 6
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NADP+ + D-Gluconic acid = NADPH + 5-Dehydro-D-gluconic acid
(links: NADP+ + (2R,3S,4R,5R) -2,3,4,5,6-pentahydroxyhexanoic acid = NADPH + (2R,3S,4S) -2,3,4,6-Tetrahydroxy-5-oxohexanoic acid)
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NADP+
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<Mapping> AtomMap:BMCCPUAPt033$BMCCPUAPt034$0
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NADPH
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1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 6 ↔ 6 7 ↔ 7 8 ↔ 8 9 ↔ 9 10 ↔ 10 11 ↔ 11 12 ↔ 12 13 ↔ 13 14 ↔ 14 15 ↔ 15 19 ↔ 19 20 ↔ 20 21 ↔ 21 22 ↔ 22 23 ↔ 23 24 ↔ 24 25 ↔ 25 26 ↔ 26 28 ↔ 28 29 ↔ 29 30 ↔ 30 31 ↔ 31 32 ↔ 32
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(2R,3S,4R,5R) -2,3,4,5,6-pentahydroxyhexanoic acid
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<Mapping> AtomMap:BMSUM6U0--07$BMSUM6Up--08$0
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(2R,3S,4S) -2,3,4,6-Tetrahydroxy-5-oxohexanoic acid
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1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 6 ↔ 6
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