LCMS:Hochuekkito

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{{LCMS/Header}}
 
== 2D-Mass chromatogram ==
 
== 2D-Mass chromatogram ==
 
[[Image:Hochuekkito_L_LC.jpg|thumb|left|425px|Mass chromatographic fingerprints of HET using Atractylodis Lanceae Rhizoma]]
 
[[Image:Hochuekkito_L_LC.jpg|thumb|left|425px|Mass chromatographic fingerprints of HET using Atractylodis Lanceae Rhizoma]]
 
[[Image:Hochuekkito_LC.jpg|thumb|425px|Mass chromatographic fingerprints of HET using Atractylodis  Rhizoma]]
 
[[Image:Hochuekkito_LC.jpg|thumb|425px|Mass chromatographic fingerprints of HET using Atractylodis  Rhizoma]]
  
−
{| class="wikitable" style="width:80%"
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{{CrudeDrug/LCMS/Neg
−
|-
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|NInstrument =Shimadzu LC-IT-TOF MS ESI
−
| Instrument || Shimadzu LC-IT-TOF MS ESI (Negative ion mode)
+
|NColumn    =Waters Atlantis T3 (2.1 mm x 150 mm)
−
|-
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|NTemperature=40
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| Column || Waters Atlantis T3 (2.1 mm x 150 mm)
+
|NSolventA  =5 mM Ammonium acetate solution
−
|-
+
|NSolventB  =acetonitrile
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| Column Temperature|| 40℃ 
+
|NGradient  =10% to 100% Solvent B (0-30 min), 100% Solvent B (30-40 min)
−
|-
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|NVoltage    =-3.5
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| Solvent A || 5 mM Ammonium acetate solution
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|NCapillary  =200
−
|-
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|NGas        =1.5
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| Solvent B || acetonitrile
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}}
−
|-
+
−
| Gradient || 10% to 100% Solvent B (0-30 min), 100% Solvent B (30-40 min)
+
−
|-
+
−
| Source voltage || – 3.5 kV
+
−
|-
+
−
| Capillary temperature || 200 °C
+
−
|-
+
−
| Nebulizer gas || 1.5 l/min
+
−
|}
+
  
 
{| class="wikitable"
 
{| class="wikitable"
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|-
 
|-
 
! {{{1|8.59}}}
 
! {{{1|8.59}}}
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
| [[{{{2|Dihydroxyflavanone-glucopyranoside}}}]] ||{{{3|Glycyrrhizae}}} || {{{4|C21H21O9}}} || {{{5|417.1150}}}
−
|-
+
−
! {{{1|8.75}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|8.97}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|9.19}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|9.49}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|10.20}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|10.43}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|11.08}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|11.31}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|11.51}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|11.65}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|12.02}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|12.36}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|12.57}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|12.60}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.12}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.18}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.31}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.40}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.65}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.64}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.76}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|13.99}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|14.23}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|14.48}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|14.71}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|14.95}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|15.70}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|16.06}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|16.13}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|17.87}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|18.88}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|19.11}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|19.19}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|20.73}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|21.39}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|22.13}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|22.73}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|23.53}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|23.75}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|24.73}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|24.81}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|25.15}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
−
|-
+
−
! {{{1|26.58}}}
+
−
| [[{{{2|Trihydroxyflavone-diglucopyranoside}}}]] ||{{{3|Aurantii Nobilis}}} || {{{4|C27H29O15}}} || {{{5|593.1495}}}
+
 
|}
 
|}

Latest revision as of 16:22, 14 February 2011

LCMS
Data List 		Names

[edit] 2D-Mass chromatogram

Mass chromatographic fingerprints of HET using Atractylodis Lanceae Rhizoma
Mass chromatographic fingerprints of HET using Atractylodis Rhizoma

[edit] Analytical conditions (Negative mode)

Instrument Shimadzu LC-IT-TOF MS ESI
Column Waters Atlantis T3 (2.1 mm x 150 mm)
Column temperature 40 °C
Solvent A 5 mM Ammonium acetate solution
Solvent B acetonitrile
Gradient 10% to 100% Solvent B (0-30 min), 100% Solvent B (30-40 min)
Source voltage -3.5 kV
Capillary temperature 200 °C
Nebulizer gas 1.5 l/min
Retention Time (min) Compounds Origin Molecular formula (M-H)- ions
8.33 Trihydroxyflavone-diglucopyranoside Aurantii Nobilis C27H29O15 593.1495
8.59 Dihydroxyflavanone-glucopyranoside Glycyrrhizae C21H21O9 417.1150
Retrieved from "http://metabolomics.jp/mediawiki/index.php?title=LCMS:Hochuekkito&oldid=284619"
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