6''-Malonoylginsenoside Rc
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(New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3beta,12beta)-20-[(6-O-alpha-L-Arabinofuranosyl-beta-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-[6-O-(carboxyacetyl)-beta-D-gl...) |
Latest revision as of 09:37, 15 February 2010
Upper classes
| IDs and Links | |
|---|---|
| LipidBank | [1] |
| LipidMaps | [2] |
| CAS | 88140-36-7 |
| KEGG | {{{KEGG}}} |
| KNApSAcK | |
| CDX file | |
| MOL file | 6''-Malonoylginsenoside Rc.mol |
| Malonylginsenoside Rc | |
|---|---|
| |
| Structural Information | |
| Systematic Name | (3beta,12beta)-20-[(6-O-alpha-L-Arabinofuranosyl-beta-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-[6-O-(carboxyacetyl)-beta-D-glucopyranosyl]-beta-D-Glucopyranoside |
| Common Name |
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| Symbol | |
| Formula | |
| Exact Mass | |
| Average Mass | |
| SMILES | |
| Physicochemical Information | |
| Melting Point | |
| Boiling Point | |
| Density | |
| Optical Rotation | |
| Reflactive Index | |
| Solubility | |
| Spectral Information | |
| Mass Spectra | |
| UV Spectra | |
| IR Spectra | |
| NMR Spectra | |
| Chromatograms | |
[edit] Spectroscopic Data
| M.P. | 150 - 152 °C |
| IR (KBr) | 3381, 2934, 1733, 1631, 1381, 1071 cm-1 |
| M.P. | 159 - 163 °C |
| 1H-NMR (C5D5N) | 0.80 (s, CH3), 0.96 (s, 3xCH3), 1.12 (s, CH3), 1.32 (s, CH3), 1.63 (s), 1.67 (s, CH3), 3.65 (s, COOCH3), 3.75 (s, OC-CH2-CO) |
| 13C-NMR (C5D5N, 22.5MHz) | C-3) 89.3, (12) 70.3, (20) 83.4 Glc I (1) 104.8, (2) 84.1, (3) 77.9, (4) 72.1, (5) 77.9, (6) 62.6 Glc II (1) 106.0, (2) 76.6, (3) 78.8, (4) 70.9, (5) 75.1, (6) 65.4 Glc III (1) 98.1, (2) 75.0, (3) 78.4, (4) 71.4, (5) 76.4, (6) 68.4 Ara(f) (1) 110.0, (2) 83.1, (3) 79.0, (4) 86.0, (5) 62.6 Malonoyl (1) 167.2, (2) 41.6, (3) 167.2, (OCH3) 52.2 |
Y. Nakagawa et al., Chem.Pharm.Bull., 37, 2961 (1989).
