Enzyme:1.8.1.5

Upper Levels: EC1.-.-.- Oxidoreductases. : EC1.8.-.- Acting on a sulfur group of donors. : EC1.8.1.- With NAD(+) or NADP(+) as acceptor.

IDs and Links
IUBMB	EC1
ExPaSy	NiceZyme 1.8.1.5

2-mercaptoethanesulfonate,acetoacetate:NADP+ oxidoreductase(decarboxylating)
Systematic Name	2-mercaptoethanesulfonate,acetoacetate:NADP+ oxidoreductase(decarboxylating)
Common Name	2-oxopropyl-CoM reductase (carboxylating) NADPH:2-(2-ketopropylthio)ethanesulfonate oxidoreductase/carboxylase NADPH:2-ketopropyl-coenzyme M oxidoreductase/carboxylase

NADP+ + 2-Mercapto-ethanesulfonate + Acetoacetic acid = NADPH + 2-Oxo-propyl-CoM + CO2 (links: NADP+ + 2-Mercapto-ethanesulfonate + CO2 + 3-Oxobutanoic acid = NADPH + 2- (2-Oxopropylsulfanyl) ethanesulfonic acid + 3-Oxobutanoic acid)

NADP+ <Mapping> AtomMap:BMCCPUAPt033$BMCCPUAPt034$0 NADPH 1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 6 ↔ 6 7 ↔ 7 8 ↔ 8 9 ↔ 9 10 ↔ 10 11 ↔ 11 12 ↔ 12 13 ↔ 13 14 ↔ 14 15 ↔ 15 19 ↔ 19 20 ↔ 20 21 ↔ 21 22 ↔ 22 23 ↔ 23 24 ↔ 24 25 ↔ 25 26 ↔ 26 28 ↔ 28 29 ↔ 29 30 ↔ 30 31 ↔ 31 32 ↔ 32 2-Mercapto-ethanesulfonate <Mapping> AtomMap:BMFYS2SFf001$BMFYB3KTf001$0 2- (2-Oxopropylsulfanyl) ethanesulfonic acid 1 ↔ 3 2 ↔ 2 3 ↔ 1 4 ↔ 4 CO2 <Mapping> AtomMap:BMXXSX--0007$BMFYS4CAp014$0 3-Oxobutanoic acid 1 ↔ 1 3-Oxobutanoic acid <Mapping> AtomMap:BMFYS4CAp014$BMFYB3KTf001$0 2- (2-Oxopropylsulfanyl) ethanesulfonic acid 2 ↔ 7 3 ↔ 6 4 ↔ 5