Enzyme:1.3.99.12

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Upper Levels: EC1.-.-.- Oxidoreductases. : EC1.3.-.- Acting on the CH-CH group of donors. : EC1.3.99.- With other acceptors.

IDs and Links
IUBMB	EC1
ExPaSy	NiceZyme 1.3.99.12

2-methylbutanoyl-CoA:(acceptor) oxidoreductase
Systematic Name	2-methylbutanoyl-CoA:(acceptor) oxidoreductase
Common Name	2-methylacyl-CoA dehydrogenase branched-chain acyl-CoA dehydrogenase 2-methyl branched chain acyl-CoA dehydrogenase

2-Methyl-butanoyl-CoA + Acceptor = 2-Methylbut-2-enoyl-CoA + Reduced acceptor
(links: S- [2- [3- [ [4- [ [ [(2R,3S,4R,5R) -5- (6-Aminopurin-9-yl) -4-hydroxy-3-phosphonooxyoxolan-2-yl] methoxy-hydroxyphosphoryl] oxy-hydroxyphosphoryl] oxy-2-hydroxy-3,3-dimethylbutanoyl] amino] propanoylamino] ethyl] 2-methylbutanethioic acid = S- [2- [3- [ [4- [ [ [(2R,3S,4R,5R) -5- (6-Aminopurin-9-yl) -4-hydroxy-3-phosphonooxyoxolan-2-yl] methoxy-hydroxyphosphoryl] oxy-hydroxyphosphoryl] oxy-2-hydroxy-3,3-dimethylbutanoyl] amino] propanoylamino] ethyl] (E) -2-methylbut-2-enethioic acid)

S- [2- [3- [ [4- [ [ [(2R,3S,4R,5R) -5- (6-Aminopurin-9-yl) -4-hydroxy-3-phosphonooxyoxolan-2-yl] methoxy-hydroxyphosphoryl] oxy-hydroxyphosphoryl] oxy-2-hydroxy-3,3-dimethylbutanoyl] amino] propanoylamino] ethyl] 2-methylbutanethioic acid	<Mapping> AtomMap:BMFYB4ESa004$BMFYB4ESa003$0	S- [2- [3- [ [4- [ [ [(2R,3S,4R,5R) -5- (6-Aminopurin-9-yl) -4-hydroxy-3-phosphonooxyoxolan-2-yl] methoxy-hydroxyphosphoryl] oxy-hydroxyphosphoryl] oxy-2-hydroxy-3,3-dimethylbutanoyl] amino] propanoylamino] ethyl] (E) -2-methylbut-2-enethioic acid
	1 ↔ 1 2 ↔ 2 3 ↔ 3 4 ↔ 4 5 ↔ 5 7 ↔ 7 8 ↔ 8 9 ↔ 9 10 ↔ 10 11 ↔ 11 12 ↔ 12 13 ↔ 13 14 ↔ 14 15 ↔ 15 16 ↔ 16 17 ↔ 17 18 ↔ 18 19 ↔ 19 20 ↔ 20 21 ↔ 21 38 ↔ 38 39 ↔ 39 40 ↔ 41 41 ↔ 40 42 ↔ 42 43 ↔ 43 44 ↔ 44 45 ↔ 45 46 ↔ 46 47 ↔ 47 48 ↔ 48 49 ↔ 49 50 ↔ 50 51 ↔ 51

2-Methyl-propanoyl-CoA + Acceptor = 2-Methylprop-2-enoyl-CoA + Reduced acceptor
(links: S- [2- [3- [ [4- [ [ [(2R,3S,4R,5R) -5- (6-Aminopurin-9-yl) -4-hydroxy-3-phosphonooxyoxolan-2-yl] methoxy-hydroxyphosphoryl] oxy-hydroxyphosphoryl] oxy-2-hydroxy-3,3-dimethylbutanoyl] amino] propanoylamino] ethyl] 2-methylpropanethioic acid = 2-Methylprop-2-enoyl-CoA)

S- [2- [3- [ [4- [ [ [(2R,3S,4R,5R) -5- (6-Aminopurin-9-yl) -4-hydroxy-3-phosphonooxyoxolan-2-yl] methoxy-hydroxyphosphoryl] oxy-hydroxyphosphoryl] oxy-2-hydroxy-3,3-dimethylbutanoyl] amino] propanoylamino] ethyl] 2-methylpropanethioic acid	<Mapping> AtomMap:BMFYB3CAa010$BMFYB3ESa001$0	2-Methylprop-2-enoyl-CoA
	1 ↔ 1 2 ↔ 2 3 ↔ 4 4 ↔ 3 6 ↔ 6 7 ↔ 7 8 ↔ 8 9 ↔ 9 10 ↔ 10 11 ↔ 11 12 ↔ 12 13 ↔ 13 14 ↔ 14 15 ↔ 15 16 ↔ 16 17 ↔ 17 18 ↔ 18 19 ↔ 19 20 ↔ 20 37 ↔ 37 38 ↔ 38 39 ↔ 40 40 ↔ 39 41 ↔ 41 42 ↔ 42 43 ↔ 43 44 ↔ 44 45 ↔ 45 46 ↔ 46 47 ↔ 47 48 ↔ 48 49 ↔ 49 50 ↔ 50

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