Category:TP5
From Metabolomics.JP
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| − | {| | + | {| class="wikitable" |
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| farnesyl diphosphate | | farnesyl diphosphate | ||
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| cyclofarnesane | | cyclofarnesane | ||
|- | |- | ||
| − | | germacrane (elemane, | + | | germacrane (elemane, lepidozane, (bi)cyclogermacrane) [http://www.pnas.org/content/95/5/2216/F1.expansion.html] |
{| class="wikitable" | {| class="wikitable" | ||
| − | | eudesmane (emmotin, oppositane, farfugin, cycloeudesmane, gorgonane, valerane/Jatamansane, spirovetivane (= vetispirane) | + | | eudesmane (emmotin, oppositane, farfugin, cycloeudesmane, gorgonane, valerane/Jatamansane, spirovetivane (= vetispirane)) |
|- | |- | ||
| − | | eremophilane ( | + | | eremophilane (chiloscyphane, aristolane, nardosinane, brasilane (?), cacalol, [http://books.google.co.jp/books?id=5BAPWB67TKUC&pg=PA107&lpg=PA107&dq=%22fukinane+biosynthesis%22&source=bl&ots=3rsiXnan_y&sig=HZGm1AsNYp7JZqtjqkf5iuY59Cg&hl=en&ei=Vs7cTs6UI8LJrAfEpvTvDA&sa=X&oi=book_result&ct=result&resnum=2&ved=0CCMQ6AEwAQ#v=onepage&q&f=false) page 133 fukinane] [[Petasites japonicus]], ishwarane |
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| − | | [http://www.orc.wur.nl/UK/Research/Bio-catalyzed+and+bio-based+synthesis+(dr.+M.C.R.+Franssen)/Sesquiterpene+biosynthesis guaiane] ( | + | | [http://www.orc.wur.nl/UK/Research/Bio-catalyzed+and+bio-based+synthesis+(dr.+M.C.R.+Franssen)/Sesquiterpene+biosynthesis guaiane] (xanthane, carabrane, pseudoguaiane, cubebane, ivaxillarane, valerenane) |
{| class="wikitable" | {| class="wikitable" | ||
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| humulane (caryyllophyllane, bicyclohumulane, [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | | humulane (caryyllophyllane, bicyclohumulane, [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | ||
|- | |- | ||
| − | + | | rowspan="2" | bisabolyl cation | |
| − | + | ||
| − | |rowspan=" | + | |
| − | + | ||
| bisabolane | | bisabolane | ||
| − | |||
{| class="wikitable" | {| class="wikitable" | ||
| − | | cuparane (herbertane [[liverwort,fungi]], laurane [[Laurencia spp. (marine)]], cyclolaurane, [http://www.springerlink.com/content/h40302g23g830241/ trichothecane] (from scirpane), gymnomitrane) | + | | cuparane (herbertane [[liverwort,fungi]], laurane [[Laurencia spp. (marine)]], cyclolaurane, [http://www.springerlink.com/content/h40302g23g830241/ trichothecane] (from scirpane), gymnomitrane, thujopsane, widdrane, ) |
| − | + | ||
| − | + | ||
|} | |} | ||
|- | |- | ||
| − | + | [http://books.google.co.jp/books?id=rIoXXL7OGCoC&pg=PA126&lpg=PA126&dq=acorane+biosynthesis&source=bl&ots=j7EPQ5aaAk&sig=m5dMiXfi-aaPjlY1OhSuYcU4oGY&hl=en&ei=veTcTpiaJYPLrQe5yMirCw&sa=X&oi=book_result&ct=result&resnum=7&ved=0CE4Q6AEwBg#v=onepage&q=acorane%20biosynthesis&f=false acorane] | |
|- | |- | ||
| − | | | + | | (Z,E)-germacradienyl cation |
| + | | cadinane (bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol, cadalane, copaane) | ||
|- | |- | ||
| + | |rowspan="2"| (Z,E)-humulyl cation | ||
| [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane] (lippifoliane, longipinane, longibornane, longifolane) | | [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane] (lippifoliane, longipinane, longibornane, longifolane) | ||
|- | |- | ||
| − | | [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (isodaucane) | + | | (proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) --> hirsutane |
| + | |- | ||
| + | | cycloheptenyl cation | ||
| + | | [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (= carotane, isodaucane) | ||
|- | |- | ||
| drimenyl cation | | drimenyl cation | ||
| [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane] (iresin, seco, coloratane) | | [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane] (iresin, seco, coloratane) | ||
| − | |||
| − | |||
| − | |||
|- | |- | ||
| furodysyl cation | | furodysyl cation | ||
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| chamigranyl cation | | chamigranyl cation | ||
| chamigrane (secochamigrane) | | chamigrane (secochamigrane) | ||
| − | |||
| − | |||
| − | |||
|- | |- | ||
| Others | | Others | ||
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| [http://alamlearning.blogspot.com/2010/11/possible-biosynthetic-pathway-for.html pinguisane], picrotoxane, perforane, pacifigorgiane, asteriscane, botrydial | | [http://alamlearning.blogspot.com/2010/11/possible-biosynthetic-pathway-for.html pinguisane], picrotoxane, perforane, pacifigorgiane, asteriscane, botrydial | ||
|} | |} | ||
| − | |||
{| class="wikitable" | {| class="wikitable" | ||
Revision as of 18:48, 10 December 2011
Contents |
Sesquiterpene (C15)
Ring configuration
Germacrane
Sesquiterpenes
Biosynthesis
Overview
- References
Sesquiterpene Synthase
| farnesyl diphosphate | |||||
| |||||
| farnesyl cation | |||||
|
| |||||
| farnesane, acyclic ones | |||||
| cyclobutane, cyclopentane | |||||
| cyclofarnesane | |||||
germacrane (elemane, lepidozane, (bi)cyclogermacrane) [1]
| |||||
| humulane (caryyllophyllane, bicyclohumulane, africanane) | |||||
| bisabolyl cation | bisabolane
| ||||
| (Z,E)-germacradienyl cation | cadinane (bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol, cadalane, copaane) | ||||
| (Z,E)-humulyl cation | himachalane (lippifoliane, longipinane, longibornane, longifolane) | ||||
| (proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) --> hirsutane | |||||
| cycloheptenyl cation | daucane (= carotane, isodaucane) | ||||
| drimenyl cation | drimane (iresin, seco, coloratane) | ||||
| furodysyl cation | furodysin (furodysinin) | ||||
| chamigranyl cation | chamigrane (secochamigrane) | ||||
| Others |
|
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