Category:TP5
From Metabolomics.JP
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=={{Bilingual|生合成|Biosynthesis}}== | =={{Bilingual|生合成|Biosynthesis}}== | ||
==={{Bilingual|概要|Overview}}=== | ==={{Bilingual|概要|Overview}}=== | ||
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;References | ;References | ||
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| eremophilane (furano-, seco-, abeo-, nor-, chiloscyphane, aristolane, nardosinane, brasilane (?), cacalol, [http://books.google.co.jp/books?id=5BAPWB67TKUC&pg=PA107&lpg=PA107&dq=%22fukinane+biosynthesis%22&source=bl&ots=3rsiXnan_y&sig=HZGm1AsNYp7JZqtjqkf5iuY59Cg&hl=en&ei=Vs7cTs6UI8LJrAfEpvTvDA&sa=X&oi=book_result&ct=result&resnum=2&ved=0CCMQ6AEwAQ#v=onepage&q&f=false) page 133 fukinane] [[Petasites japonicus]], ishwarane | | eremophilane (furano-, seco-, abeo-, nor-, chiloscyphane, aristolane, nardosinane, brasilane (?), cacalol, [http://books.google.co.jp/books?id=5BAPWB67TKUC&pg=PA107&lpg=PA107&dq=%22fukinane+biosynthesis%22&source=bl&ots=3rsiXnan_y&sig=HZGm1AsNYp7JZqtjqkf5iuY59Cg&hl=en&ei=Vs7cTs6UI8LJrAfEpvTvDA&sa=X&oi=book_result&ct=result&resnum=2&ved=0CCMQ6AEwAQ#v=onepage&q&f=false) page 133 fukinane] [[Petasites japonicus]], ishwarane | ||
| + | |- | ||
| + | | [http://www.orc.wur.nl/UK/Research/Bio-catalyzed+and+bio-based+synthesis+(dr.+M.C.R.+Franssen)/Sesquiterpene+biosynthesis guaiane] (guaianolide, dimer, seco, abeo, xanthane, carabrane, pseudoguaiane, cubebane, ivaxillarane, valerenane) | ||
| + | |||
| + | {| class="wikitable" | ||
| + | | cycloguaiane (aromadendrane, patchoulane, rotundane, bourbonane) | ||
| + | |} | ||
| + | |- | ||
|} | |} | ||
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| nerolidyl cation | | nerolidyl cation | ||
|- | |- | ||
| − | |rowspan=" | + | |rowspan="6"| |
|- | |- | ||
| bisabolane | | bisabolane | ||
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|- | |- | ||
| cadinane (nor, seco, bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol) | | cadinane (nor, seco, bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol) | ||
| − | |||
| − | |||
| − | |||
| − | |||
| − | |||
| − | |||
| − | |||
| − | |||
| − | |||
|- | |- | ||
| [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane] (lippifoliane, longipinane, longibornane, longifolane) | | [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane] (lippifoliane, longipinane, longibornane, longifolane) | ||
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| [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (isodaucane) | | [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (isodaucane) | ||
|- | |- | ||
| + | | drimenyl cation | ||
| + | | [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane] (iresin, seco, coloratane) | ||
| + | |- | ||
| + | | illudyl cation | ||
| (proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) | | (proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) | ||
|- | |- | ||
| + | | furodysyl cation | ||
| furodysin (furodysinin) | | furodysin (furodysinin) | ||
|- | |- | ||
| + | | chamigranyl cation | ||
| chamigrane (secochamigrane) | | chamigrane (secochamigrane) | ||
|- | |- | ||
| + | | | ||
| [http://books.google.co.jp/books?id=rIoXXL7OGCoC&pg=PA126&lpg=PA126&dq=acorane+biosynthesis&source=bl&ots=j7EPQ5aaAk&sig=m5dMiXfi-aaPjlY1OhSuYcU4oGY&hl=en&ei=veTcTpiaJYPLrQe5yMirCw&sa=X&oi=book_result&ct=result&resnum=7&ved=0CE4Q6AEwBg#v=onepage&q=acorane%20biosynthesis&f=false acorane] | | [http://books.google.co.jp/books?id=rIoXXL7OGCoC&pg=PA126&lpg=PA126&dq=acorane+biosynthesis&source=bl&ots=j7EPQ5aaAk&sig=m5dMiXfi-aaPjlY1OhSuYcU4oGY&hl=en&ei=veTcTpiaJYPLrQe5yMirCw&sa=X&oi=book_result&ct=result&resnum=7&ved=0CE4Q6AEwBg#v=onepage&q=acorane%20biosynthesis&f=false acorane] | ||
|- | |- | ||
| Others | | Others | ||
| − | + | | | |
{| class="wikitable" | {| class="wikitable" | ||
| [http://alamlearning.blogspot.com/2010/11/possible-biosynthetic-pathway-for.html pinguisane], picrotoxane, perforane, pacifigorgiane, asteriscane, botrydial | | [http://alamlearning.blogspot.com/2010/11/possible-biosynthetic-pathway-for.html pinguisane], picrotoxane, perforane, pacifigorgiane, asteriscane, botrydial | ||
Revision as of 12:53, 9 December 2011
Contents |
Sesquiterpene (C15)
Ring configuration
Germacrane
Sesquiterpenes
Biosynthesis
Overview
- References
Sesquiterpene Synthase
| farnesyl diphosphate | |||||
| |||||
| farnesyl cation | |||||
|
| |||||
| farnesane, acyclic ones | |||||
| cyclobutane, cyclopentane | |||||
| cyclofarnesane | |||||
germacrane (elemane, 12-6/12-8 germacranolide, furano- nor- homo- seco-germacrane, bicyclogermacrane, lepidozane) [1]
| |||||
| humulane (caryyllophyllane, bicyclohumulane, africanane) | |||||
| nerolidyl cation | |||||
bisabolane
| |||||
| cycloheptenyl cation | |||||
| cadinane (nor, seco, bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene, oplopane, mutisianthol) | |||||
| himachalane (lippifoliane, longipinane, longibornane, longifolane) | |||||
| daucane (isodaucane) | |||||
| drimenyl cation | drimane (iresin, seco, coloratane) | ||||
| illudyl cation | (proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) | ||||
| furodysyl cation | furodysin (furodysinin) | ||||
| chamigranyl cation | chamigrane (secochamigrane) | ||||
| acorane | |||||
| Others |
|
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