Category:TP5
From Metabolomics.JP
(Difference between revisions)
(→{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}) |
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* bicyclogermacrane<br/>[[Image:Bicyclogermacrane.png|90px]] | * bicyclogermacrane<br/>[[Image:Bicyclogermacrane.png|90px]] | ||
| eudesmane (= selinane)<br/>[[Image:Eudesmanyl cation.png|100px]]<!---[[Image:beta-Selinene.png|80px]]--> | | eudesmane (= selinane)<br/>[[Image:Eudesmanyl cation.png|100px]]<!---[[Image:beta-Selinene.png|80px]]--> | ||
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* cycloeudesmane<br/>[[Image:Cycloeudesmane.png|85px]] | * cycloeudesmane<br/>[[Image:Cycloeudesmane.png|85px]] | ||
* elemane ... 7,8 seco form<br/>[[Image:Elemene.png|85px]] | * elemane ... 7,8 seco form<br/>[[Image:Elemene.png|85px]] | ||
* emmotin ... 14(10→1) abeo form<br/>[[Image:Emmotin.png|85px]] | * emmotin ... 14(10→1) abeo form<br/>[[Image:Emmotin.png|85px]] | ||
* farfugin ... 14(10→9) abeo form<br/>[[Image:Farfugin.png|85px]] | * farfugin ... 14(10→9) abeo form<br/>[[Image:Farfugin.png|85px]] | ||
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* gorgonane 11(7→6) abeo form<br/>[[Image:Gorgonane.png|70px]] | * gorgonane 11(7→6) abeo form<br/>[[Image:Gorgonane.png|70px]] | ||
* oppositane ... 8(7→6) abeo form<br/>[[Image:Oppositane.png|85px]] | * oppositane ... 8(7→6) abeo form<br/>[[Image:Oppositane.png|85px]] | ||
* valerane (= jatamansane) 15(4→5) abeo form<br/>[[Image:Valerane.png|85px]] | * valerane (= jatamansane) 15(4→5) abeo form<br/>[[Image:Valerane.png|85px]] | ||
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| vetispiradienyl cation<br/>[[Image:Vetispiradienyl_cation.png|90px]] | | vetispiradienyl cation<br/>[[Image:Vetispiradienyl_cation.png|90px]] | ||
* vetispiradiene<br/>[[Image:Vetispiradiene.png|80px]] | * vetispiradiene<br/>[[Image:Vetispiradiene.png|80px]] | ||
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|- | |- | ||
| eremophilane (= 14(10→5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]] | | eremophilane (= 14(10→5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]] | ||
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* aristolochene<br/>[[Image:5-epi-Aristolochene.png|85px]] | * aristolochene<br/>[[Image:5-epi-Aristolochene.png|85px]] | ||
* aristolane ... 6,11-cyclo form<br/>[[Image:Aristolane.png|80px]] | * aristolane ... 6,11-cyclo form<br/>[[Image:Aristolane.png|80px]] | ||
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* nardosinane ... 11(7→6) abeo form<br/>[[Image:Nardosinane.png|70px]] | * nardosinane ... 11(7→6) abeo form<br/>[[Image:Nardosinane.png|70px]] | ||
* cacalol ... 14(5→6) abeo form<br/>[[Image:Cacalol.png|85px]] | * cacalol ... 14(5→6) abeo form<br/>[[Image:Cacalol.png|85px]] | ||
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* fukinane ... 9(8→7) abeo form<br/>[[Image:Fukinane.png|85px]] [[Petasites japonicus]] | * fukinane ... 9(8→7) abeo form<br/>[[Image:Fukinane.png|85px]] [[Petasites japonicus]] | ||
* brasilane<br/>[[Image:Brasilane.png|75px]] | * brasilane<br/>[[Image:Brasilane.png|75px]] | ||
− | | | + | * thapsane<br/>[[Image:Thapsane.png|85px]] |
− | + | * ishwarane<br/>[[Image:Ishwarane.png|60px]] | |
|- | |- | ||
| [http://www.orc.wur.nl/UK/Research/Bio-catalyzed+and+bio-based+synthesis+(dr.+M.C.R.+Franssen)/Sesquiterpene+biosynthesis guaiane]<br/>[[Image:Guaiane.png|85px]] | | [http://www.orc.wur.nl/UK/Research/Bio-catalyzed+and+bio-based+synthesis+(dr.+M.C.R.+Franssen)/Sesquiterpene+biosynthesis guaiane]<br/>[[Image:Guaiane.png|85px]] | ||
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* xanthane ... 4,5 seco form<br/>[[Image:Xanthane.png|70px]] | * xanthane ... 4,5 seco form<br/>[[Image:Xanthane.png|70px]] | ||
* carabrane ... 4,5 seco form<br/>[[Image:Carabrane.png|70px]] | * carabrane ... 4,5 seco form<br/>[[Image:Carabrane.png|70px]] | ||
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* pseudoguaiane ... 15(4→5) abeo form<br/>[[Image:Pseudoguaiane.png|70px]] | * pseudoguaiane ... 15(4→5) abeo form<br/>[[Image:Pseudoguaiane.png|70px]] | ||
* valerenane ... 8(7→6) abeo form<br/>[[Image:Valerenane.png|75px]] | * valerenane ... 8(7→6) abeo form<br/>[[Image:Valerenane.png|75px]] | ||
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| | | | ||
cycloguaiane | cycloguaiane | ||
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* cubebane ... 1,6-cyclo form<br/>[[Image:Cubebane.png|80px]] | * cubebane ... 1,6-cyclo form<br/>[[Image:Cubebane.png|80px]] | ||
* ivaxillarane ... 8,10-cyclo form<br/>[[Image:Ivaxillarane.png|80px]] | * ivaxillarane ... 8,10-cyclo form<br/>[[Image:Ivaxillarane.png|80px]] | ||
* aromadendrane ... 6,11- cyclo form<br/>[[Image:Aromadendrane.png|70px]] | * aromadendrane ... 6,11- cyclo form<br/>[[Image:Aromadendrane.png|70px]] | ||
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* rotundane ... 10,12-cyclo form<br/>[[Image:Rotundane.png|60px]] | * rotundane ... 10,12-cyclo form<br/>[[Image:Rotundane.png|60px]] | ||
* patchoulane ... 1,11-cyclo form<br/>[[Image:Patchoulane.png|60px]] | * patchoulane ... 1,11-cyclo form<br/>[[Image:Patchoulane.png|60px]] | ||
* bourbonane ... 6,10-cyclo form<br/>[[Image:Bourbonane.png|80px]] | * bourbonane ... 6,10-cyclo form<br/>[[Image:Bourbonane.png|80px]] | ||
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|- | |- | ||
|rowspan="2"| (E,E)-humulane<br/>[[Image:(E,E)-Humulyl cation.png|100px]] | |rowspan="2"| (E,E)-humulane<br/>[[Image:(E,E)-Humulyl cation.png|100px]] | ||
* bicyclohumulane<br/>[[Image:Bicyclohumulane.png|80px]] | * bicyclohumulane<br/>[[Image:Bicyclohumulane.png|80px]] | ||
| caryophyllane<br/>[[Image:(E)-beta-Caryophyllene.png|80px]] | | caryophyllane<br/>[[Image:(E)-beta-Caryophyllene.png|80px]] | ||
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| [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]<br/>[[Image:Africanane.png|80px]] | | [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]<br/>[[Image:Africanane.png|80px]] | ||
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|- | |- | ||
| [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane]<br/>[[Image:Drimane.png|100px]] | | [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane]<br/>[[Image:Drimane.png|100px]] | ||
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| chamigrane ... 6,11-cyclobisabolane<br/>[[Image:Chamigrane.png|90px]] | | chamigrane ... 6,11-cyclobisabolane<br/>[[Image:Chamigrane.png|90px]] | ||
* acorane ... 6,10-cyclobisabolane<br/>[[Image:Acorane.png|80px]] | * acorane ... 6,10-cyclobisabolane<br/>[[Image:Acorane.png|80px]] | ||
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|- | |- | ||
| cuparane (= 7,11-cyclobisabolane)<br/>[[Image:Cuparane.png|95px]] | | cuparane (= 7,11-cyclobisabolane)<br/>[[Image:Cuparane.png|95px]] | ||
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| (Z,E)-germacradiene<br/>[[Image:(Z,E)-Germacradienyl cation.png|100px]] | | (Z,E)-germacradiene<br/>[[Image:(Z,E)-Germacradienyl cation.png|100px]] | ||
| cadinane<br/>[[Image:Cadinane.png|90px]] | | cadinane<br/>[[Image:Cadinane.png|90px]] | ||
− | |||
− | |||
* muurolane<br/>[[Image:Muurolane.png|80px]] | * muurolane<br/>[[Image:Muurolane.png|80px]] | ||
* bulgarane<br/>[[Image:Bulgarane.png|80px]] | * bulgarane<br/>[[Image:Bulgarane.png|80px]] | ||
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* calamenene<br/>[[Image:Calamenene.png|80px]] | * calamenene<br/>[[Image:Calamenene.png|80px]] | ||
* cadalane<br/>[[Image:Cadalane.png|80px]] | * cadalane<br/>[[Image:Cadalane.png|80px]] | ||
− | |||
* alliacane ... 2(3→4) abeo cadinane<br/>[[Image:Alliacane.png|80px]] | * alliacane ... 2(3→4) abeo cadinane<br/>[[Image:Alliacane.png|80px]] | ||
* primnatriene ... 2(3→4) abeo cadinane<br/>[[Image:Primnatriene.png|80px]] | * primnatriene ... 2(3→4) abeo cadinane<br/>[[Image:Primnatriene.png|80px]] | ||
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* mutisianthol ... 6(7→8) abeo cadinane<br/>[[Image:Mutisianthol.png|90px]] | * mutisianthol ... 6(7→8) abeo cadinane<br/>[[Image:Mutisianthol.png|90px]] | ||
* copaane ... 5,10 cyclo cadinane<br/>[[Image:Copaane.png|80px]] | * copaane ... 5,10 cyclo cadinane<br/>[[Image:Copaane.png|80px]] | ||
− | |||
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|- | |- | ||
|rowspan="2"| (Z,E)-humulane<br/>[[Image:(Z,E)-Humulyl cation.png|100px]] | |rowspan="2"| (Z,E)-humulane<br/>[[Image:(Z,E)-Humulyl cation.png|100px]] | ||
| [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane]<br/>[[Image:Himachalane.png|85px]] | | [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane]<br/>[[Image:Himachalane.png|85px]] | ||
− | + | * lippifoliane<br/>[[Image:Lippifoliane.png|80px]] | |
− | + | * longipinane<br/>[[Image:Longipinane.png|75px]] | |
− | * lippifoliane | + | * longibornane<br/>[[Image:Longibornane.png|75px]] |
− | * longipinane | + | * longifolane<br/>[[Image:Longifolane.png|70px]]<!--[[Image:(+)-Longifolene.png|60px]]--> |
− | + | ||
− | * longibornane | + | |
− | * longifolane | + | |
− | + | ||
|- | |- | ||
| protoilludane<br/>[[Image:Protoilludane.png|95px]] | | protoilludane<br/>[[Image:Protoilludane.png|95px]] | ||
− | |||
− | |||
* illudane<br/>[[Image:Illudane.png|85px]] | * illudane<br/>[[Image:Illudane.png|85px]] | ||
* illudalane ... 4,6-secoilludane<br/>[[Image:Illudalane.png|85px]] | * illudalane ... 4,6-secoilludane<br/>[[Image:Illudalane.png|85px]] | ||
* sterpurane ... 5(6→7)-abeoilludane<br/>[[Image:Sterpurane.png|85px]] | * sterpurane ... 5(6→7)-abeoilludane<br/>[[Image:Sterpurane.png|85px]] | ||
* isolactarane<br/>[[Image:Isolactarane.png|85px]] | * isolactarane<br/>[[Image:Isolactarane.png|85px]] | ||
− | |||
* merulane<br/>[[Image:Merulane.png|85px]] | * merulane<br/>[[Image:Merulane.png|85px]] | ||
* lactarane<br/>[[Image:Lactarane.png|85px]] | * lactarane<br/>[[Image:Lactarane.png|85px]] | ||
* marasmane<br/>[[Image:Marasmane.png|75px]] | * marasmane<br/>[[Image:Marasmane.png|75px]] | ||
− | | | + | | hirsutane<br/>[[Image:Hirsutane.png|90px]] |
− | + | ||
|- | |- | ||
| cycloheptenyl cation<br/>[[Image:Cycloheptenyl cation.png|100px]] | | cycloheptenyl cation<br/>[[Image:Cycloheptenyl cation.png|100px]] | ||
| [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (= carotane)<br/>[[Image:Daucane.png|90px]] | | [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (= carotane)<br/>[[Image:Daucane.png|90px]] | ||
* isodaucane<br/>[[Image:Isodaucane.png|70px]] | * isodaucane<br/>[[Image:Isodaucane.png|70px]] | ||
− | |||
− | |||
|- | |- | ||
| furodysin<br/>[[Image:Furodysin.png|120px]] | | furodysin<br/>[[Image:Furodysin.png|120px]] | ||
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|- | |- | ||
| botrydial<br/>[[Image:Botrydial.png|100px]] | | botrydial<br/>[[Image:Botrydial.png|100px]] | ||
+ | |} | ||
+ | |||
+ | {| class="wikitable" | ||
+ | | tricyclic | ||
+ | {| | ||
+ | |- | ||
+ | * cedrane<br/>[[Image:Cedrane.png|80px]] | ||
+ | * isocedrane<br/>[[Image:Isocedrane.png|80px]] | ||
+ | * zizaane<br/>[[Image:Zizaane.png|80px]] | ||
+ | * prezizaane<br/>[[Image:Prezizaane.png|80px]] | ||
+ | * clovane<br/>[[Image:Clovane.png|80px]] | ||
+ | * precapnellane<br/>[[Image:Precapnellane.png|80px]] | ||
+ | * capnellane<br/>[[Image:Capnellane.png|80px]] | ||
+ | * pentalenane<br/>[[Image:Pentalenane.png|80px]] | ||
+ | * silphinane<br/>[[Image:Silphinane.png|80px]] | ||
+ | * silphiperfoliane<br/>[[Image:Silphiperfoliane.png|80px]] | ||
+ | * presilphiperfolane<br/>[[Image:Presilphiperfolane.png|80px]] | ||
+ | * isocomane<br/>[[Image:Isocomane.png|80px]] | ||
+ | * panasinsane<br/>[[Image:Panasinsane.png|80px]] | ||
+ | * modhephane<br/>[[Image:Modhephane.png|80px]] | ||
+ | * quadrane<br/>[[Image:Quadrane.png|80px]] | ||
+ | * campherenane<br/>[[Image:Campherenane.png|80px]] | ||
+ | * alpha-santalane<br/>[[Image:alpha-Santalane.png|80px]] | ||
+ | * beta-santalane<br/>[[Image:beta-Santalane.png|80px]] | ||
+ | * sativane<br/>[[Image:Sativane.png|80px]] | ||
+ | * helminthosporane<br/>[[Image:Helminthosporane.png|80px]] | ||
+ | * copacamphane<br/>[[Image:Copacamphane.png|80px]] | ||
+ | * cyclocopacamphane<br/>[[Image:Cyclocopacamphane.png|80px]] | ||
+ | * sinularane<br/>[[Image:Sinularane.png|80px]] | ||
+ | * cyclosinularane<br/>[[Image:Cyclosinularane.png|80px]] | ||
|- | |- | ||
− | |||
|} | |} |
Revision as of 16:46, 20 December 2011
Contents |
Sesquiterpene (C15)
Ring configuration
Germacrane
Sesquiterpenes
Biosynthesis
Overview
- References
Sesquiterpene Synthase
farnesyl diphosphate![]() | ||||||||
![]() | ||||||||
farnesyl cation![]() |
| |||||||
(E,E)-germacradiene![]() |
eudesmane (= selinane)![]() |
vetispiradienyl cation![]() | ||||||
eremophilane (= 14(10→5) abeoeudesmane)![]()
| ||||||||
guaiane![]() |
cycloguaiane | |||||||
(E,E)-humulane![]() |
caryophyllane![]() | |||||||
africanane![]() | ||||||||
drimane![]() |
||||||||
nerolidyl cation![]() |
bisabolane![]() |
chamigrane ... 6,11-cyclobisabolane![]() | ||||||
cuparane (= 7,11-cyclobisabolane)![]()
|
trichothecane [1]![]()
| |||||||
(Z,E)-germacradiene![]() |
cadinane![]() | |||||||
(Z,E)-humulane![]() |
himachalane![]() | |||||||
protoilludane![]() |
hirsutane![]() | |||||||
cycloheptenyl cation![]() |
daucane (= carotane)![]() | |||||||
furodysin![]() | ||||||||
others |
|
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