Category:TP5

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Line 108: Line 108:
 
|rowspan="2"| bisabolane<br/>[[Image:Bisabolyl cation.png|100px]]
 
|rowspan="2"| bisabolane<br/>[[Image:Bisabolyl cation.png|100px]]
 
* thujopsane<br/>[[Image:(-)-Sesquithujene.png|80px]]
 
* thujopsane<br/>[[Image:(-)-Sesquithujene.png|80px]]
−
| chamigrane ... 6,11-cyclobisabolane<br/>[[Image:Chamigrane|80px]]
+
| chamigrane ... 6,11-cyclobisabolane<br/>[[Image:Chamigrane.png|80px]]
−
* acorane ... 6,10-cyclobisabolane<br/>[[Image:Acorane|60px]]
+
* acorane ... 6,10-cyclobisabolane<br/>[[Image:Acorane.png|70px]]
 
|-
 
|-
−
| cuparane (= 7,11-cyclobisabolane)
+
| cuparane (= 7,11-cyclobisabolane)<br/>[[Image:Cuparane.png|70px]]
−
* herbertane [[liverwort,fungi]] ... 15(3&rarr;4) abeo form
+
* herbertane [[liverwort,fungi]] ... 15(3&rarr;4) abeo form<br/>[[Image:Herbertane.png|70px]]
−
* laurane [[Laurencia spp. (marine)]] ... 13(11&rarr;10) abeo form
+
* laurane [[Laurencia spp. (marine)]] ... 13(11&rarr;10) abeo form<br/>[[Image:Laurane.png|70px]]
−
| trichothecane <ref>Grove JF "Non-Macrocyclic Trichothecenes" Nat Prod Rep 5:187-209, 1988</ref>
+
* cyclolaurane <br/>[[Image:Cyclolaurane.png|70px]]
 +
| trichothecane <ref>Grove JF "Non-Macrocyclic Trichothecenes" Nat Prod Rep 5:187-209, 1988</ref><br/>[[Image:Trichothecane.png|70px]]
 
{|
 
{|
−
| gymnomitrane
+
| gymnomitrane<br/>[[Image:Gymnomitrane.png|70px]]
 
| widdrane
 
| widdrane
 
|}
 
|}

Revision as of 17:17, 15 December 2011

Contents

Sesquiterpene (C15)

Ring configuration

Germacrane


Sesquiterpenes

Biosynthesis

Overview

References


Sesquiterpene Synthase

farnesyl diphosphate
Farnesyl diphosphate.png
Arrow00d35.png
farnesyl cation
Farnesyl cation.png
farnesane, acyclic ones cyclobutane, cyclopentane cyclofarnesan
(E,E)-germacradiene
(E,E)-Germacradienyl cation.png
  • germacrane
    Germacrene A.png
  • lepidozane
    Lepidozane.png
  • bicyclogermacrane
    Bicyclogermacrane.png
eudesmane (= selinane)
Eudesmanyl cation.png
  • cycloeudesmane
    Cycloeudesmane.png
  • elemane ... 7,8 seco form
    Elemene.png
  • emmotin ... 14(10→1) abeo form
    Emmotin.png
  • farfugin ... 14(10→9) abeo form
    Farfugin.png
  • gorgonane 11(7→6) abeo form
    Gorgonane.png
  • oppositane ... 8(7→6) abeo form
    Oppositane.png
  • valerane (= jatamansane) 15(4→5) abeo form
    Valerane.png
vetispiradienyl cation
Vetispiradienyl cation.png
  • vetispiradiene
    Vetispiradiene.png
  • spirovetivane (= vetispirane)
    Spirovetivane.png
eremophilane (= 14(10→5) abeoeudesmane)
Eremophilenyl cation.png
  • aristolochene
    5-epi-Aristolochene.png
  • aristolane ... 6,11-cyclo form
    Aristolane.png
  • chiloscyphane ...8(7→6) abeo form
    Chiloscyphane.png
  • nardosinane ... 11(7→6) abeo form
    Nardosinane.png
  • cacalol ... 14(5→6) abeo form
    Cacalol.png
  • fukinane ... 9(8→7) abeo form
    Fukinane.png Petasites japonicus
  • brasilane
    Brasilane.png
  • thapsane
    Thapsane.png
  • ishwarane
    Ishwarane.png
guaiane
Guaiane.png
  • xanthane ... 4,5 seco form
    Xanthane.png
  • carabrane ... 4,5 seco form
    Carabrane.png
  • pseudoguaiane ... 15(4→5) abeo form
    Pseudoguaiane.png
  • valerenane ... 8(7→6) abeo form
    Valerenane.png

Cycloguaiane

  • cubebane ... 1,6-cyclo form
    Cubebane.png
  • ivaxillarane ... 8,10-cyclo form
    Ivaxillarane.png
  • aromadendrane ... 6,11- cyclo form
    Aromadendrane.png
  • rotundane ... 10,12-cyclo form
    Rotundane.png
  • patchoulane ... 1,11-cyclo form
    Patchoulane.png
  • bourbonane ... 6,10-cyclo form
    Bourbonane.png
(E,E)-humulane
(E,E)-Humulyl cation.png
  • bicyclohumulane
    Bicyclohumulane.png
africanane
Africanane.png
caryophyllane
(E)-beta-Caryophyllene.png
drimane
Drimane.png
  • iresin
    Iresin.png
  • coloratane
    Coloratane.png
nerolidyl cation
Nerolidyl cation.png 		bisabolane
Bisabolyl cation.png
  • thujopsane
    (-)-Sesquithujene.png
chamigrane ... 6,11-cyclobisabolane
Chamigrane.png
  • acorane ... 6,10-cyclobisabolane
    Acorane.png
cuparane (= 7,11-cyclobisabolane)
Cuparane.png 		trichothecane [1]
Trichothecane.png
gymnomitrane
Gymnomitrane.png 		widdrane
(Z,E)-germacradiene
(Z,E)-Germacradienyl cation.png 		cadinane
Cadinane.png
  • muurolane
    Muurolane.png
  • bulgarane
    Bulgarane.png
  • amorphane
    Amorphane.png
  • calamenene
    Calamenene.png
  • cadalane
    Cadalane.png
  • alliacane ... 2(3→4) abeo cadinane
    Alliacane.png
  • primnatriene ... 2(3→4) abeo cadinane
    Primnatriene.png
  • oplopane ... 3(4→5) abeo cadinane
    Oplopane.png
  • mutisianthol ... 6(7→8) abeo cadinane
    Mutisianthol.png
  • copaane ... 5,10 cyclo cadinane
    Copaane.png
(Z,E)-humulane
(Z,E)-Humulyl cation.png 		himachalane
Himachalane.png
  • lippifoliane
    Lippifoliane.png
  • longipinane
    Longipinane.png
  • longibornane
    Longibornane.png
  • longifolane
    Longifolane.png
protoilludane
Protoilludane.png
  • illudane
    Illudane.png
  • illudalane ... 4,6-secoilludane
    Illudalane.png
  • sterpurane ... 5(6→7)-abeoilludane
    Sterpurane.png
  • isolactarane
    Isolactarane.png
  • merulane
    Merulane.png
  • lactarane
    Lactarane.png
  • marasmane
    Marasmane.png
hirsutane
Hirsutane.png
cycloheptenyl cation
Cycloheptenyl cation.png 		daucane (= carotane)
Daucane.png
  • isodaucane
    Isodaucane.png
furodysin
Furodysin.png
  • furodysinin
    Furodysinin.png
others
pinguisane
Pinguisane.png
picrotoxane
Picrotoxane.png
perforane
Perforane.png
pacifigorgiane
Pacifigorgiane.png
asteriscane
Asteriscane.png
botrydial
Botrydial.png
tricyclic
  • cedrane
    Cedrane.png
  • isocedrane
    Isocedrane.png
  • zizaane
    Zizaane.png
  • prezizaane
    Prezizaane.png

Cite error: <ref> tags exist, but no <references/> tag was found

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