Category:TP5

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Line 64: Line 64:
 
* oppositane ... 8(7→6) abeo form
 
* oppositane ... 8(7→6) abeo form
 
* valerane (= jatamansane) 15(4→5) abeo form
 
* valerane (= jatamansane) 15(4→5) abeo form
−
|  vetispiradienyl_cation<br/>[[Image:Vetispiradienyl_cation.png|80px]] &rarr; spirovetivane (= vetispirane)
+
|  vetispiradienyl cation<br/>[[Image:Vetispiradienyl_cation.png|80px]]
 +
* vetispiradiene<br/>[[Image:Vetispiradiene.png|60px]]
 +
* spirovetivane (= vetispirane)<br/>[[Image:Spirovetivane.png|60px]]
 
|-
 
|-
 
| eremophilane (= 14(10&rarr;5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]]
 
| eremophilane (= 14(10&rarr;5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]]

Revision as of 14:43, 13 December 2011

Contents

Sesquiterpene (C15)

Ring configuration

Germacrane


Sesquiterpenes

Biosynthesis

Overview

References


Sesquiterpene Synthase

farnesyl diphosphate
Farnesyl diphosphate.png
Arrow00d35.png
farnesyl cation
Farnesyl cation.png
farnesane, acyclic ones cyclobutane, cyclopentane cyclofarnesane
(E,E)-germacradiene
(E,E)-Germacradienyl cation.png
  • germacrane
    Germacrene A.png
  • lepidozane
    Lepidozane.png
  • bicyclogermacrane
    Bicyclogermacrane.png
eudesmane (= selinane)
Eudesmanyl cation.png
  • cycloeudesmane
  • elemane ... 7,8 seco form
  • emmotin ... 14(10→1) abeo form
  • farfugin ... 14(10→9) abeo form
  • gorgonane 11(7→6) abeo form
  • oppositane ... 8(7→6) abeo form
  • valerane (= jatamansane) 15(4→5) abeo form
vetispiradienyl cation
Vetispiradienyl cation.png
  • vetispiradiene
    Vetispiradiene.png
  • spirovetivane (= vetispirane)
    Spirovetivane.png
eremophilane (= 14(10→5) abeoeudesmane)
Eremophilenyl cation.png
  • aristolane ... 6,11-cyclo form
    5-epi-Aristolochene.png
  • chiloscyphane ...8(7→6) abeo form
  • nardosinane ... 11(7→6) abeo form
  • brasilane?
  • cacalol ... 14(5→6) abeo form
  • fukinane ... 9(8→7) abeo form
    Petasites japonicus
  • ishwarane?
guaiane
  • xanthane, carabrane ... 4,5 seco form
  • pseudoguaiane ... 15(4→5) abeo form
  • valerenane ... 8(7→6) abeo form

Cycloguaiane

  • cubebane ... 1,6-cyclo form
  • ivaxillarane ... 8,10-cyclo form
  • aromadendrane ... 6,11- cyclo form
  • rotundane ... 10,12-cyclo form
  • bourbonane ... 6,10-cyclo form
  • patchoulane ... 1,11-cyclo form
(E,E)-humulane
(E,E)-Humulyl cation.png
  • bicyclohumulane
africanane
caryophyllane
(E)-beta-Caryophyllene.png
drimane
Drimane.png
  • iresin
    Iresin.png
  • coloratane
    Coloratane.png
nerolidyl cation
Nerolidyl cation.png 		bisabolane
Bisabolyl cation.png
  • thujopsane
    (-)-Sesquithujene.png
  • acorane ... 6,10-cyclobisabolane
  • chamigrane ... 6,11-cyclobisabolane
cuparane (= 7,11-cyclobisabolane) trichothecane [1]
gymnomitrane widdrane
(Z,E)-germacradiene
(Z,E)-Germacradienyl cation.png 		cadinane
(+)-delta-Cadinene.png
  • bulgarane, calamenene, muurolane, amorphane, cadalane
  • alliacane/primnatriene ... 2(3→4) abeo cadinane
  • oplopane ... 3(4→5) abeo cadinane
  • mutisianthol ... 6(7→8) abeo cadinane
  • copaane ... 5,10 cyclo cadinane
(Z,E)-humulane
(Z,E)-Humulyl cation.png 		himachalane
  • lippifoliane
  • longipinane
  • longibornane
  • longifolane
    (+)-Longifolene.png
protoilludane
  • illudane
  • illudalane ... 4,6-secoilludane
  • sterpurane ... 5(6→7)-abeoilludane
  • lactarane, isolactarane, marasmane, merulane
hirsutane
cycloheptenyl cation
Cycloheptenyl cation.png 		daucane (= carotane)
Daucane.png
  • isodaucane
    Isodaucane.png
furodysin
Furodysin.png
  • furodysinin
    Furodysinin.png
others
pinguisane
Pinguisane.png
picrotoxane
Picrotoxane.png
perforane
Perforane.png
pacifigorgiane
Pacifigorgiane.png
asteriscane
Asteriscane.png
botrydial
Botrydial.png
tricyclic
  • cedrane
    Cedrane.png
  • isocedrane
    Isocedrane.png
  • zizaane
    Zizaane.png
  • prezizaane
    Prezizaane.png

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