Category:TP5
From Metabolomics.JP
(Difference between revisions)
(→{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}) |
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|rowspan="3"|(E,E)-germacradiene<br/>[[Image:(E,E)-Germacradienyl cation.png|100px]] | |rowspan="3"|(E,E)-germacradiene<br/>[[Image:(E,E)-Germacradienyl cation.png|100px]] | ||
| − | * germacrane [[Image:Germacrene A.png|80px]] | + | * germacrane<br/>[[Image:Germacrene A.png|80px]] |
* lepidozane | * lepidozane | ||
* bicyclogermacrane | * bicyclogermacrane | ||
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* oppositane ... 8(7→6) abeo form | * oppositane ... 8(7→6) abeo form | ||
* valerane (= jatamansane) 15(4→5) abeo form | * valerane (= jatamansane) 15(4→5) abeo form | ||
| − | | vetispiradienyl_cation [[Image:Vetispiradienyl_cation.png|80px]] → spirovetivane (= vetispirane) | + | | vetispiradienyl_cation<br/>[[Image:Vetispiradienyl_cation.png|80px]] → spirovetivane (= vetispirane) |
|- | |- | ||
| eremophilane (= 14(10→5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]] | | eremophilane (= 14(10→5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]] | ||
| − | * aristolane ... 6,11-cyclo form [[Image:5-epi-Aristolochene.png|80px]] | + | * aristolane ... 6,11-cyclo form<br/>[[Image:5-epi-Aristolochene.png|80px]] |
* chiloscyphane ...8(7→6) abeo form | * chiloscyphane ...8(7→6) abeo form | ||
* nardosinane ... 11(7→6) abeo form | * nardosinane ... 11(7→6) abeo form | ||
* brasilane? | * brasilane? | ||
* cacalol ... 14(5→6) abeo form | * cacalol ... 14(5→6) abeo form | ||
| − | * fukinane ... 9(8→7) abeo form [[Petasites japonicus]] | + | * fukinane ... 9(8→7) abeo form<br/>[[Petasites japonicus]] |
* ishwarane? | * ishwarane? | ||
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* [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | * [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | ||
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| − | | caryophyllane<br/> [[Image:(E)-beta-Caryophyllene.png|60px]] | + | | caryophyllane<br/>[[Image:(E)-beta-Caryophyllene.png|60px]] |
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|rowspan="7"| nerolidyl cation<br/>[[Image:Nerolidyl cation.png|100px]] | |rowspan="7"| nerolidyl cation<br/>[[Image:Nerolidyl cation.png|100px]] | ||
|rowspan="2"| bisabolane<br/>[[Image:Bisabolyl cation.png|100px]] | |rowspan="2"| bisabolane<br/>[[Image:Bisabolyl cation.png|100px]] | ||
| − | * thujopsane [[Image:(-)-Sesquithujene.png|80px]] | + | * thujopsane<br/>[[Image:(-)-Sesquithujene.png|80px]] |
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* acorane ... 6,10-cyclobisabolane | * acorane ... 6,10-cyclobisabolane | ||
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* longipinane | * longipinane | ||
* longibornane | * longibornane | ||
| − | * longifolane [[Image:(+)-Longifolene.png|80px]] | + | * longifolane<br/>[[Image:(+)-Longifolene.png|80px]] |
|- | |- | ||
| protoilludane | | protoilludane | ||
Revision as of 11:18, 13 December 2011
Contents |
Sesquiterpene (C15)
Ring configuration
Germacrane
Sesquiterpenes
Biosynthesis
Overview
- References
Sesquiterpene Synthase
farnesyl diphosphate
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farnesyl cation
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(E,E)-germacradiene-Germacradienyl_cation.png)
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eudesmane (= selinane) 
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vetispiradienyl_cation → spirovetivane (= vetispirane)
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eremophilane (= 14(10→5) abeoeudesmane)
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guaiane
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Cycloguaiane
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(E,E)-humulane-Humulyl_cation.png)
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africanane | ||||
caryophyllane-beta-Caryophyllene.png)
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drimane
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nerolidyl cation
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bisabolane
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cuparane (= 7,11-cyclobisabolane)
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trichothecane [1]
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(Z,E)-germacradiene-Germacradienyl_cation.png)
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cadinane -delta-Cadinene.png)
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(Z,E)-humulane-Humulyl_cation.png)
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himachalane
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protoilludane
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hirsutane | ||||
cycloheptenyl cation
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daucane (= carotane, isodaucane) | ||||
furodysin
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| Others |
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-Sesquithujene.png)
-Longifolene.png)
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