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Koryoginsenoside-R1 - Revision history
2026-06-22T06:42:14Z
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Toyama at 03:59, 16 February 2010
2010-02-16T03:59:56Z
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<td colspan='2' style="background-color: white; color:black;">← Older revision</td>
<td colspan='2' style="background-color: white; color:black;">Revision as of 03:59, 16 February 2010</td>
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<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>{{Metabolite</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>{{Metabolite</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="background: #ffa; color:black; font-size: smaller;"><div>|SysName=(E)-(3beta,6alpha,12beta)-3,12-Dihydroxy-6-<del class="diffchange diffchange-inline">[[</del>6-O-(1-oxo-2-butenyl)-beta-D-glucopyranosyl<del class="diffchange diffchange-inline">]</del>oxy<del class="diffchange diffchange-inline">]</del>dammar-24-en-20-<del class="diffchange diffchange-inline">ylbeta</del>-D-<del class="diffchange diffchange-inline">glucopyranoside</del></div></td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div>|SysName=(E)-(3beta,6alpha,12beta)-3,12-Dihydroxy-6-<ins class="diffchange diffchange-inline">((</ins>6-O-(1-oxo-2-butenyl)-beta-D-glucopyranosyl<ins class="diffchange diffchange-inline">)</ins>oxy<ins class="diffchange diffchange-inline">)</ins>dammar-24-en-20-<ins class="diffchange diffchange-inline">yl beta</ins>-D-<ins class="diffchange diffchange-inline">Glucopyranoside</ins></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|Common Name=&&Koryoginsenoside R1&&</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|Common Name=&&Koryoginsenoside R1&&</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|CAS=171674-97-8</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|CAS=171674-97-8</div></td></tr>
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Toyama
http://metabolomics.jp/mediawiki/index.php?title=Koryoginsenoside-R1&diff=106149&oldid=prev
Toyama: New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(E)-(3beta,6alpha,12beta)-3,12-Dihydroxy-6-[[6-O-(1-oxo-2-butenyl)-beta-D-glucopyranosyl]oxy]dammar-24-en-20-ylbeta-D-glucopyranoside |Com...
2010-02-16T03:50:53Z
<p>New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(E)-(3beta,6alpha,12beta)-3,12-Dihydroxy-6-[[6-O-(1-oxo-2-butenyl)-beta-D-glucopyranosyl]oxy]dammar-24-en-20-ylbeta-D-glucopyranoside |Com...</p>
<p><b>New page</b></p><div>{{Hierarchy|{{PAGENAME}}}}<br />
<br />
{{Metabolite<br />
|SysName=(E)-(3beta,6alpha,12beta)-3,12-Dihydroxy-6-[[6-O-(1-oxo-2-butenyl)-beta-D-glucopyranosyl]oxy]dammar-24-en-20-ylbeta-D-glucopyranoside<br />
|Common Name=&&Koryoginsenoside R1&&<br />
|CAS=171674-97-8<br />
|KNApSAcK=<br />
}}<br />
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==Spectroscopic Data==<br />
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{| class="wikitable" style="width:80%"<br />
|-<br />
| '''IR''' (KBr)|| 3500-3300 (OH), 2930 (CH), 1710 (conjugated CO, ester), 1640, 1440, 1380, 1300 cm<sup>-1</sup><br />
|-<br />
| '''<sup>1</sup>H-NMR''' (C<sub>5</sub>D<sub>5</sub>N, 400 MHz)|| 0.94 (s, 3xH-30), 1.07 (s, 3xH-19), 1.39 (s, 3xH-18), 1.52 (s, 3xH-29), 1.62 (s, 3xH-26 and 3xH-27), 1.63 (s, 3xH-21), 1.75 (d, ''J''=6.6 Hz, 3xH-4 of But), 2.01 (s, 3xH-28), 3.46 (dd, ''J''=11.5, 4.6 Hz, H-3), 4.11 (m, H-12), 4.37 (dd, ''J''=10.5, 3.6 Hz, H-6), 5.01 (d, ''J''=7.6 Hz, H-1 of Glc I), 5.15 (d, ''J''=7.8 Hz, H-1 of Glc II), 5.27 (t, ''J''=6.7 Hz, H-24), 6.02 (d, ''J''=15.6 Hz, H-2 of But), 7.06 (dq, ''J''=15.6, 7.0 Hz, H-3 of But)<br />
|-<br />
| '''<sup>13</sup>C-NMR''' (C<sub>5</sub>D<sub>5</sub>N, 100MHz)|| C-1) 39.6, (2) 27.9, (3) 78.8, (4) 40.3, (5) 61.5, (6) 80.0, (7) 45.6, (8) 41.4, (9) 50.1, (10) 39.8, (11) 31.0, (12) 70.3, (13) 49.3, (14) 51.5, (15) 31.1, (16) 26.8, (17) 51.8, (18) 17.7, (19) 17.6, (20) 83.4, (21) 22.4, (22) 36.2, (23) 23.3, (24) 126.0, (25) 131.0, (26) 25.8, (27) 17.8, (28) 31.6, (29) 16.5, (30) 17.4 '''Glc I''' (1) 106.1, (2) 75.5, (3) 79.2, (4) 71.8, (5) 75.2, (6) 65.1 '''But''' (1) 166.6, (2) 123.3, (3) 144.7, (4) 17.6 '''Glc II''' (1) 98.3, (2) 75.2, (3) 79.2, (4) 71.6, (5) 78.2, (6) 63.1 <br />
|}<br />
<small>C.-R. Yang et al., Phytochemistry, 40, 1493 (1995).</small></div>
Toyama