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Ginsenoside Rc - Revision history
2026-05-04T13:25:53Z
Revision history for this page on the wiki
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http://metabolomics.jp/mediawiki/index.php?title=Ginsenoside_Rc&diff=106077&oldid=prev
Toyama at 01:39, 16 February 2010
2010-02-16T01:39:14Z
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<td colspan='2' style="background-color: white; color:black;">Revision as of 01:39, 16 February 2010</td>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;"></ins></div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">==Spectroscopic Data==</ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;"></ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">{| class="wikitable" style="width:80%"</ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">'''Free acid'''</ins></div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">| '''M.P.'''<sup>1</sup> || 199 - 201 °C </ins></div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">| '''IR''' (KBr)<sup>1</sup>|| 3400 (OH), 1620 (C=C) cm<sup>-1</sup></ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">|-</ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">| '''<sup>13</sup>C-NMR''' (C<sub>5</sub>D<sub>5</sub>N, 25.15MHz)<sup>2</sup>|| C-1) 39.0, (2) 26.6, (3) 89.0, (4) 39.6, (5) 56.3, (6) 18.3, (7) 35.1, (8) 39.9, (9) 50.1, (10) 36.8, (11) 30.7, (12) 70.2, (13) 49.5, (14) 51.4, (15) 30.8, (16) 26.6, (17) 51.6, (18) 16.2, (19) 15.9, (20) 83.1, (21) 22.2, (22) 36.0, (23) 23.1, (24) 125.9, (25) 130.9, (26) 25.7, (27) 17.8, (28) 28.0, (29) 16.5, (30) 17.3 '''Glc I''' (1) 104.9, (2) 83.1, (3) 77.8, (4) 71.5, (5) 77.8, (6) 62.6 '''Glc II''' (1) 105.6, (2) 76.8, (3) 78.7, (4) 71.5, (5) 78.0, (6) 62.6 Glc III (1) 97.9, (2) 74.9, (3) 78.0, (4) 71.5, (5) 76.3, (6) 68.3 '''Ara(f)''' (1) 109.9, (2) 83.3, (3) 78.9, (4) 85.8, (5) 62.6</ins></div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">{| class="wikitable" style="width:80%"</ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">'''Permethyl ester'''</ins></div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">| '''<sup>1</sup>H-NMR''' (C<sub>5</sub>D<sub>5</sub>N, 100 MHz)<sup>1</sup>|| 0.80-1.00 (5xCH<sub>3</sub>), 1.29 (s, CH<sub>3</sub>), 1.59 (s, CH<sub>3</sub>), 1.67 (s, CH<sub>3</sub>), 3.31-3.61 (13xOCH<sub>3</sub>), 4.23 (d, ''J''=8.0 Hz, anomeric H), 4.47, 4.67 (each d, ''J''=7.0 Hz, 2 x anomeric H), 5.00 (s, H-5 of Ara(f))</ins></div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;"><small>1) S. Shibata et al., Chem.Pharm.Bull., 22, 421 (1974)., 2) T. Fuwa et al., Chem.Pharm.Bull., 31, 2120 (1983).</small></ins></div></td></tr>
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Toyama
http://metabolomics.jp/mediawiki/index.php?title=Ginsenoside_Rc&diff=106076&oldid=prev
Toyama at 03:43, 19 December 2009
2009-12-19T03:43:37Z
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<td colspan='2' style="background-color: white; color:black;">Revision as of 03:43, 19 December 2009</td>
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<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>{{Metabolite</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>{{Metabolite</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="background: #ffa; color:black; font-size: smaller;"><div>|SysName=(<del class="diffchange diffchange-inline">3.beta.</del>,<del class="diffchange diffchange-inline">12.beta.</del>)-20-[(6-O-<del class="diffchange diffchange-inline">.</del>alpha<del class="diffchange diffchange-inline">.</del>-L-Arabinofuranosyl-<del class="diffchange diffchange-inline">.</del>beta<del class="diffchange diffchange-inline">.</del>-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-<del class="diffchange diffchange-inline">.</del>beta<del class="diffchange diffchange-inline">.</del>-D-glucopyranosyl-<del class="diffchange diffchange-inline">.</del>beta<del class="diffchange diffchange-inline">.</del>-D-glucopyranoside</div></td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div>|SysName=(<ins class="diffchange diffchange-inline">3beta</ins>,<ins class="diffchange diffchange-inline">12beta</ins>)-20-[(6-O-alpha-L-Arabinofuranosyl-beta-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-beta-D-glucopyranosyl-beta-D-glucopyranoside</div></td></tr>
<tr><td class='diff-marker'>−</td><td style="background: #ffa; color:black; font-size: smaller;"><div>|Common Name=&&Ginsenoside Rc&&<del class="diffchange diffchange-inline">.</del>beta<del class="diffchange diffchange-inline">.</del>-D-Glucopyranoside deriv.<del class="diffchange diffchange-inline">dammarane</del>&&Panaxoside Rc&&</div></td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div>|Common Name=&&Ginsenoside Rc&&<ins class="diffchange diffchange-inline">dammarane </ins>beta-D-Glucopyranoside deriv.&&Panaxoside Rc&&</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|CAS=11021-14-0</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>|CAS=11021-14-0</div></td></tr>
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Toyama
http://metabolomics.jp/mediawiki/index.php?title=Ginsenoside_Rc&diff=106075&oldid=prev
Toyama: New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3.beta.,12.beta.)-20-[(6-O-.alpha.-L-Arabinofuranosyl-.beta.-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-.beta.-D-glucopyranosy...
2009-12-14T07:54:42Z
<p>New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3.beta.,12.beta.)-20-[(6-O-.alpha.-L-Arabinofuranosyl-.beta.-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-.beta.-D-glucopyranosy...</p>
<p><b>New page</b></p><div>{{Hierarchy|{{PAGENAME}}}}<br />
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{{Metabolite<br />
|SysName=(3.beta.,12.beta.)-20-[(6-O-.alpha.-L-Arabinofuranosyl-.beta.-D-glucopyranosyl)oxy]-12-hydroxydammar-24-en-3-yl 2-O-.beta.-D-glucopyranosyl-.beta.-D-glucopyranoside<br />
|Common Name=&&Ginsenoside Rc&&.beta.-D-Glucopyranoside deriv.dammarane&&Panaxoside Rc&&<br />
|CAS=11021-14-0<br />
|KNApSAcK=<br />
}}</div>
Toyama