Category:TP5 - Revision history

Adm: /* {{Bilingual|概要|Overview}} */

2014-07-22T04:17:58Z

‎{{Bilingual|概要|Overview}}

2014-07-22T04:16:28Z

‎{{Bilingual|生合成|Biosynthesis}}

2014-07-22T00:58:54Z

2012-03-27T04:54:05Z

‎{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}

2011-12-20T07:46:22Z

2011-12-19T16:10:13Z

‎{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}

2011-12-19T04:17:03Z

2011-12-15T08:26:10Z

2011-12-15T08:24:42Z

2011-12-15T08:22:12Z

@@ Line 27: / Line 27: @@
 {| class="wikitable" style="text-align:right"
 ! Substrate || Type || Intermediate
-| rowspan="3"| Farnesyl diphosphate (FPP)<br/>[[Image:Farnesyl_diphosphate.png]]
+|-
 | Transoid synthase on (2-''trans'',6-''trans'')-FPP<br/>
 | [[Image:Farnesyl_cation.png]]

@@ Line 25: / Line 25: @@
 Cisoid synthase first isomerizes C2-C3 double bond to produce the neutral (3'R')- or (3'S')-nerolidyl diphosphate (enzyme-bound) and then ionizes it.
-{|
+{| class="wikitable" style="text-align:right"
-! Type || Substrate
+! Substrate || Type || Intermediate
-| Transoid synthase
+| rowspan="3"| Farnesyl diphosphate (FPP)<br/>[[Image:Farnesyl_diphosphate.png]]
-|(2-'trans',6-'trans')-farnesyl diphosphate
+| Transoid synthase on (2-''trans'',6-''trans'')-FPP<br/>
 |-
-| Cisoid synthase
+| Cisoid synthase on (2-''cis'',6-''trans'')-FPP<br/>
-|((2-'cis',6-'trans')-farnesyl diphosphate
+| (nerolidyl cation)<br/>[[Image:Nerolidyl_cation.png]]
 |}

← Older revision		Revision as of 00:58, 22 July 2014
Line 21:		Line 21:
	=={{Bilingual\|生合成\|Biosynthesis}}==		=={{Bilingual\|生合成\|Biosynthesis}}==
	==={{Bilingual\|概要\|Overview}}===		==={{Bilingual\|概要\|Overview}}===
		+	Two major classes of terpene synthases exist: "transoid" and "cisoid" synthase.
		+	Transoid synthase directly ionizes ('trans','trans')-farnesyl diphosphate, whereas
		+	Cisoid synthase first isomerizes C2-C3 double bond to produce the neutral (3'R')- or (3'S')-nerolidyl diphosphate (enzyme-bound) and then ionizes it.
		+
		+	{\|
		+	! Type \|\| Substrate
		+	\| Transoid synthase
		+	\|(2-'trans',6-'trans')-farnesyl diphosphate
		+	\|-
		+	\| Cisoid synthase
		+	\|((2-'cis',6-'trans')-farnesyl diphosphate
		+	\|}
		+

@@ Line 44: / Line 44: @@
 <!---FARNESYL--->
 |-
-|rowspan="7" align="center"| farnesyl cation<br/>[[Image:Farnesyl cation.png|100px]]
+|rowspan="7" align="center" valign="top"| farnesyl cation<br/>[[Image:Farnesyl cation.png|100px]]
 |colspan="2"|
 {|
@@ Line 52: / Line 52: @@
 |}
 |-
-|rowspan="3"|(E,E)-germacradiene<br/>[[Image:(E,E)-Germacradienyl cation.png|100px]]
+|rowspan="3" valign="top"|(E,E)-germacradiene<br/>[[Image:(E,E)-Germacradienyl cation.png]]
 * germacrane<br/>[[Image:Germacrene A.png|90px]]
 * lepidozane<br/>[[Image:Lepidozane.png|90px]]
 * bicyclogermacrane<br/>[[Image:Bicyclogermacrane.png|90px]]
-| eudesmane (= selinane)<br/>[[Image:Eudesmanyl cation.png|100px]]<!---[[Image:beta-Selinene.png|80px]]-->
+| eudesmane (= selinane)<br/>[[Image:Eudesmanyl cation.png]]<!---[[Image:beta-Selinene.png|80px]]-->
 * cycloeudesmane<br/>[[Image:Cycloeudesmane.png|85px]]
 * elemane ... 7,8 seco form<br/>[[Image:Elemene.png|85px]]
@@ Line 64: / Line 66: @@
 * oppositane ... 8(7&rarr;6) abeo form<br/>[[Image:Oppositane.png|85px]]
 * valerane (= jatamansane) 15(4&rarr;5) abeo form<br/>[[Image:Valerane.png|85px]]
-|  vetispiradienyl cation<br/>[[Image:Vetispiradienyl_cation.png|90px]]
+|valign="top"|vetispiradienyl cation<br/>[[Image:Vetispiradienyl_cation.png|90px]]
 * vetispiradiene<br/>[[Image:Vetispiradiene.png|80px]]
 * spirovetivane (= vetispirane)<br/>[[Image:Spirovetivane.png|80px]]

@@ Line 95: / Line 95: @@
 |rowspan="2"| (E,E)-humulane<br/>[[Image:(E,E)-Humulyl cation.png|100px]]
 * bicyclohumulane<br/>[[Image:Bicyclohumulane.png|80px]]
 | caryophyllane<br/>[[Image:(E)-beta-Caryophyllene.png|80px]]
 |-
 | [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane]<br/>[[Image:Drimane.png|100px]]

@@ Line 112: / Line 112: @@
 |-
 | cuparane (= 7,11-cyclobisabolane)<br/>[[Image:Cuparane.png|95px]]
-* herbertane [[liverwort,fungi]] ... 15(3&rarr;4) abeo form<br/>[[Image:Herbertane.png|85px]]
+* herbertane [[liverwort,fungi]] ... 15(3&rarr;4) abeo form<br/>[[Image:Herbertane.png|80px]]
 * laurane [[Laurencia spp. (marine)]] ... 13(11&rarr;10) abeo form<br/>[[Image:Laurane.png|90px]]
 * cyclolaurane <br/>[[Image:Cyclolaurane.png|85px]]

@@ Line 85: / Line 85: @@
 * valerenane ... 8(7&rarr;6) abeo form<br/>[[Image:Valerenane.png|75px]]
+|
-Cycloguaiane
+cycloguaiane
 * cubebane ...  1,6-cyclo form<br/>[[Image:Cubebane.png|80px]]
 * ivaxillarane ... 8,10-cyclo form<br/>[[Image:Ivaxillarane.png|80px]]
@@ Line 115: / Line 115: @@
 * laurane [[Laurencia spp. (marine)]] ... 13(11&rarr;10) abeo form<br/>[[Image:Laurane.png|90px]]
 * cyclolaurane <br/>[[Image:Cyclolaurane.png|85px]]
-| trichothecane <ref>Grove JF "Non-Macrocyclic Trichothecenes" Nat Prod Rep 5:187-209, 1988</ref><br/>[[Image:Trichothecane.png|45px]]
+| trichothecane <ref>Grove JF "Non-Macrocyclic Trichothecenes" Nat Prod Rep 5:187-209, 1988</ref><br/>[[Image:Trichothecane.png|50px]]
 {|
-| gymnomitrane<br/>[[Image:Gymnomitrane.png|70px]]
+| widdrane<!--structure not shown<br/>[[Image:Widdrane.png|70px]]-->
-| widdrane
 |}
 |-